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Reaction of ( t -Bu 2 SnO) 3 with Organohalosilanes. Simple Formation of Open-Chain and Cyclic Stannasiloxanes †

✍ Scribed by Beckmann, Jens; Mahieu, Bernard; Nigge, Walter; Schollmeyer, Dieter; Schürmann, Markus; Jurkschat, Klaus


Book ID
126155198
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
587 KB
Volume
17
Category
Article
ISSN
0276-7333

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The unexpected formation of open-chain thioesters (3) and ( 6) from the reaction of 2-lithio-r-2-t-4-t-6-trimethyl (1-Li) and 2-lithio-r-2-phenyl-t-4-t-6-dimethyl-1,3-dithiane (4-Li), respectively, with chlorodiphenylphosphane followed by oxidation was observed instead of the anticipated gem-derivat