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Reaction of symmetrical derivatives of B-mercurated carboranes with nucleophilic reagents

โœ Scribed by V. I. Bregadze; V. Ts. Kampel'; N. N. Godovikov

Book ID
112480338
Publisher
Springer
Year
1981
Tongue
English
Weight
275 KB
Volume
30
Category
Article
ISSN
1573-9171

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The reaction of [3-oxonitrones --imidazoline derivatives --with hydroxylamine, phenylhydrazine, and semicarbazide takes place at the carbonyl group with retention of the nitrone group. Stable nitroxyl radicals --spiroimidazoisoxazole derivatives -are formed in the oxidation of fJhydroximinonitrones.