Reaction of stable ylids of arsenic with ketones
β Scribed by N. A. Nesmeyanov; E. V. Binshtok; O. A. Rebrova; O. A. Reutov
- Book ID
- 112422839
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 148 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Despite the very extensive study currently beiw devoted to the development of arirldine chemistry, little information is available on aziridine ylid derivatives (1). In view of this, aziridinium ylids may be of particular interest, and to investigate the properties of aziridinium ylids, we have stud
Nucleophiles such as hydride and hydroxide have previously been shown to readily react with pyrimidinium salts, and the products of these reactions can be rationalized on the basis of nucleophilic attack at the 2-position of the heterocycle (1,2,3).
Phosphorus ylids find great utility in synthesis where the best known reactions such as the Wittig and variants thereof are used for the construction of carbon-carbon bonds.' We now report a new, sinple reaction of ~tho~carbonylalkylidenephosphoranes with singlet oxygen to