𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reaction of silylketene acetals with 3,3-dimethylacryloyl chloride.

✍ Scribed by Gérard Rousseau; Luis Blanco

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
106 KB
Volume
26
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of silylketene acetals with 3,3_dimethylacryloyi chloride in acetonitrile gave y,6-ethylenic P-keto esters 2. Application to a new synthesis of (?)-turmzrone

📜 SIMILAR VOLUMES

Reaction of peroxyacetals with silyl ket
Reaction of peroxyacetals with silyl ketene acetals: synthesis of 3-peroxyalkanoates and 3-peroxyalkanals
✍ P.H Dussault; R.J Lee; J.A Schultz; Y.S Suh 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 163 KB

Lewis acid-mediated reaction of monoperoxyacetals with silyl ketene acetals (SKAs) provides an ecient approach to 3-peroxyalkanoates. Propionate SKAs react with aliphatic peroxyacetals to furnish 3-peroxy-2-methyl alkanoates with modest anti-selectivity. Although acetate and thioacetate SKAs are les

Lewis acid promoted reaction of acetals
Lewis acid promoted reaction of acetals with η3-crotyltitanium reagents
✍ Nadine Thery; Jan Szymoniak; Claude Moïse 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 229 KB

In the presence of Lewis acids, q3-crotyltitanocene reagents react with acetals to give homoallylic ethers in moderate to good yields. In all cases the reactions proceed with total T-regioselectivity. The diastereoselectivity for aliphatic acetals is no longer observed in comparison with the total a

Reaction of Perchloro-1,3,5-trisilacyclo
Reaction of Perchloro-1,3,5-trisilacyclohexane with Methylmagnesium Chloride
✍ Prof. Dr. G. Fritz; Dr. N. Szczepanski 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB 👁 2 views

of 12 e 1 kcal mole-1 for reaction (1); this value is somewhat smaller than that reported [I], wilhout error limits, for 100 atrn. From the pressure dependence at 23OC, in conjunction with Eq. (2), a volume change, AV, associated with the reaction of 64 f 3 ml/mole is obtained. Both A H and A V decr