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Reaction of silylene with allenes: Alkylidenesilacyclopropane and silatrimethylenemethane

✍ Scribed by Wataru Ando; Haruo Saso

Book ID
104219362
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
246 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of photogenerated dimesitylsilylene

with tertbutyldimethylallene and tert-butylallene yielded the corresponding alkylidenesilacyclopropanes.

Its photochemical behavior and some reactions with nucleophiles are described.

Because of the unique properties resulting from high strain energy, the studies of silicon-containing three-membered ring compounds have been fruitful

in recent silicon chemistry. ') Alkylidenesilacyclopropanes are specially suited targets for such strained silicon compounds, because of the unique structural

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