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Reaction of pyrophosphites with carboxylate esters

✍ Scribed by I. S. Alfer'ev; S. Yu. Bobkov; I. L. Kotlyarevskii

Book ID
112446080
Publisher
Springer
Year
1987
Tongue
English
Weight
308 KB
Volume
36
Category
Article
ISSN
1573-9171

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## Abstract Sodium cyanide in hexamethylphosphoric triamide selectively cleaves methyl esters in the presence of ethyl esters with yields of __ca.__ 80%. The mechanism of the reaction has been investigated. It consists of nucleophilic displacement by cyanide of the carboxylate ion from the alcohol