Sulfur ylides generated from the reactio
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
โ
Yuri N Romashin; Michael T.H Liu; Brian T Hill; Matthew S Platz
๐
Article
๐
2003
๐
Elsevier Science
๐
French
โ 153 KB
Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide for