Reaction of p-toluenesulfonyl isocyanate with polymers having amide moieties and hydrolysis of the obtained polymers

Synthesis and radical polymerization of

Synthesis and radical polymerization of a vinyl monomer having a sulfonylacylurea moiety and hydrolysis of the obtained polymer

✍ Takeru Iwamura; Ikuyoshi Tomita; Masato Suzuki; Takeshi Endo 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 2 views

The radical polymerization of N-acryloyl-N-(p-tolylsulfonyl)urea ( 2), prepared easily by the reaction of p-toluenesulfonyl isocyanate with acrylamide, was carried out in DMF, DMSO, or NMP at 60ЊC by use of AIBN as an initiator to give a polymer 3 in a good yield. Copolymerization parameters of 2 we