Received in Japan IO April 1975; received in UK for publioation I WY 1975) Recently, many reports have appeared dealing with new applications of alkalimetall-alkynyltriorganoborates readily available from organoboranes for the synthesis of a wide variety of organic compounds.'-" We have previously p
Reaction of organoboranes with methoxycarbene, and reaction of dichloromethyl methyl ether with at-complex obtained from organoboranes and methyl lithium
β Scribed by Akira Suzuki; Seichi Nozawa; Norio Miyaura; Mitsuomi Itoh; Herbert C. Brown
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 183 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Recently, numerous papers describing new organic syntheses by means of organoboranes have been published (1). The majority of such reactions apparently arise from the fact that
π SIMILAR VOLUMES
1,1,2-Trihalocyclopropanes (halogen= chlorine or bromine) undergo 1,2dehalogenation on reaction with methyl lithium, and in a number of cases the product is a 1-halocyclopropene. In the reactionsof (20, X = Br, Cl) and ( 25) a rearrangement occurs even at low temperatures and propargylic halides are
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