The oxidation of norbornene (la) by chromyl chloride has recently been carried out by Freeman et al. as part of a kinetic study of the mechanism of oxidation by this reagent (1). Unfortunately no product analysis was made. We have repeated this reaction and the products
Reaction of norbornenes with phenylpalladium chloride
β Scribed by Hiroshi Horino; Mannosuke Arai; Naoto Inoue
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 208 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The addition of phenyl(trichloromethyl)mercury to five substituted norbornenes is described, and the results compared with those obtained with bicyclo[2.2.2]octβ2βene and 3,3,5,5βtetramethylcyclopentene. The reaction proves to be useful for synthetic purposes, in that it leads usually t
El-and (Z)-RCH=CHSiMe3(R=Ph, n-C6H13, CH30CH2) reacted stereospecifically with Ph-Pd-OAc to give RCH=C(Ph)SiMe3 and R(Ph)C=CHSiMe3 with inversion of the starting geometry with respect to R and Me3Si groups. Alkenylsilanes are known to react regio-and stereospecifically with a wide range of electroph