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Reaction of nitrogen and sulphur compounds during catalytic hydrotreatment of shale oil

✍ Scribed by P.T Williams; H.M Chishti


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
141 KB
Volume
80
Category
Article
ISSN
0016-2361

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✦ Synopsis


Pyrolysis oil derived from oil shale was hydrotreated in a stirred reactor at 4008C for a hydrotreatment time of 12 h. The in¯uence of hydrogen pressure at 7, 9, 11 and 15 MPa and the role of catalyst type in the form of nickel±molybdenum and cobalt±molybdenum types was investigated in relation to the yield and composition of the products. The results showed that nitrogen and sulphur contents of the hydrotreated oils were signi®cantly decreased after hydrotreatment and were further decreased with increasing pressure of hydrogen. Correspondingly, detailed analysis of the oils showed that the aromatic nitrogen and sulphur containing compounds were decreased in concentration in the oils as the hydrogen pressure was increased. The comparison of catalyst types showed that there was little difference in the denitrogenation and desulphurisation ef®ciency of the two catalysts.


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