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Reaction of neodymium diiodide with methanol in acetonitrile. Structure of the cluster [Nd4(μ2-I)1.1(μ3-I)(μ2-OMe)4.9(μ4-O)(MeCN)12]I3

✍ Scribed by D. M. Kuzyaev; G. K. Fukin; E. V. Baranov; M. N. Bochkarev


Book ID
106520641
Publisher
Springer
Year
2007
Tongue
English
Weight
287 KB
Volume
56
Category
Article
ISSN
1573-9171

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✍ Yu-Jun Shi; Yan Xu; Xue-Tai Chen; Ziling Xue; Xiao-Zeng You 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 103 KB 👁 1 views

A novel lead(II) cluster [Pb 7 (µ 3 -O)(µ 4 -O)(µ 3 -OMe) 4 (µ 2 -I) 4 ]I 2 (1) has been isolated from the reaction mixture of PbI 2 and pyrazine in DMF/MeOH solvent with a reasonable yield (46%). The X-ray crystallography shows that 1 exhibits a novel unprecedented cage structure with centered µ 3