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Reaction of molybdenum—molybdenum triple bonded compounds with group VIII peroxo-transition metal complexes

✍ Scribed by Henri Arzoumanian; André Baldy; Marcel Pierrot; Jean-François Petrignani

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
317 KB
Volume
294
Category
Article
ISSN
0022-328X

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Treatment of I-hydroxy[2.2]paracyclophane (1) with the Mim-(4). This dienone dimerizes at room temperature to afford the oun molybdenum oxodiperoxo complex [Mo(O&O] . Py . Diels-Alder adduct 5, whose structure was confirmed by X-ray HMPT gives 3,4-dihydro-3-hydroxy-4-oxo[2.2]paracyclophane analysis.