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Reaction of molybdenum hexacarbonyl with disulphides

โœ Scribed by R.N. Jowitt; P.C.H. Mitchell

Publisher
Elsevier Science
Year
1968
Weight
174 KB
Volume
4
Category
Article
ISSN
0020-1650

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Reaction of Tungsten Hexacarbonyl with A
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โœ Priv.-Doz. Dr. W. Beck; Dipl.-Chem. H. S. Smedal ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 137 KB ๐Ÿ‘ 2 views

Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether