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Reaction of Methane with Nickel Hydride Complexes Yielding Methyl Derivatives

✍ Scribed by Tatiana B. Rubtsova; Nikolai V. Kirjakov; Grigorii L. Soloveichik; Alexander E. Shilov

Book ID
111729471
Publisher
Royal Society of Chemistry
Year
1993
Tongue
English
Weight
219 KB
Volume
3
Category
Article
ISSN
0959-9436

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πŸ“œ SIMILAR VOLUMES

Activation of reducing agents. Sodium hy
Activation of reducing agents. Sodium hydride containing complex reducing agents 22. New coupling reaction with β€œnickel doped” complex reducing agent.
✍ RΓ©gis Vanderesse; Yves Fort; Sandrine Becker; Paul Caubere πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 178 KB

Vinyl halides can be coupled by NiCRA-bpy in THF or hexane. Interestingly simply changing the solvent changes the nature of the product : diene in THF, and enyne in hexane. Metal promoted homocoupling of vinyl halides continues to be actively studied on account of its wide range of synthetic applic