✦ LIBER ✦

Reaction of metal-carbene complexes with diazoalkanes. A versatile vinyl ether synthesis.

✍ Scribed by Charles P. Casey; Steven H. Bertz; Terry J. Burkhardt

Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 157 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95959-3

No coin nor oath required. For personal study only.

✦ Synopsis

In developing new approaches to the use of stable transition metal-carbene complexes in organic synthesis, we have focused our attention of the M&+ ylide nature of the metal-carbene bond and on the susceptibility of the electron deficient carbene carbon atom to nucleophilic attack.' In this regard, we (CO),W=C' R 8 e/R 0 ,R AC3), administered by the American Chemical Society.

📜 SIMILAR VOLUMES

Reaction of aryl chromium carbene comple

Reaction of aryl chromium carbene complexes with ethyl propiolate a versatile vinyl ether formation

✍ Ayako Yamashita; Terrence A. Scahill 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 183 KB

Synthesis of η2-Allene Complexes by the

Synthesis of η2-Allene Complexes by the Reaction of a η1-Vinylidene Tungsten Complex with Diazoalkanes

✍ Junes Ipaktschi; Parham Rooshenas; Ansgar Dülmer 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB

A new synthesis of spiroacetals via alky

A new synthesis of spiroacetals via alkylidenation of ester carbonyls with metal carbene complexes

✍ Michael Mortimore; Philip Kocieński 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 261 KB

Synthesis of a poly(vinyl ether) contain

Synthesis of a poly(vinyl ether) containing a benzocyclobutene moiety and its reaction with dienophiles

✍ Keisuke Chino; Toshikazu Takata; Takeshi Endo 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB 👁 2 views

1-Benzocyclobutenyl vinyl ether (1) was easily prepared by the elimination reaction of hydrogen bromide from 1-benzocyclobutenyl 1-bromoethyl ether obtained by 1-bromobenzocyclobutene and ethylene glycol via two steps in a good yield. Cationic polymerizations of 1 was carried out at Ϫ78°C for 2 h in

ChemInform Abstract: Reactions of Comple

ChemInform Abstract: Reactions of Complex Ligands. Part 78. [2 + 1] Cycloadditions of Diazoalkanes to Enol Ethers Catalyzed by Chromium Complexes — The First Direct Spectroscopic Observation of a Carbene Complex Intermediate.

✍ J. PFEIFFER; K. H. DOETZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Synthesis of Oligo(isobutyl vinyl ether)

Synthesis of Oligo(isobutyl vinyl ether) with a Silyl Enol Ether End Group and their Aldol Reactions with Benzaldehyde

✍ Prodip K. Sarker; Stephen Rimmer 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB

## Abstract **Summary:** Cationic polymerizations of isobutyl vinyl ether (__i__BVE) were carried out in the presence of a difunctional silyl enol ether, 3,3‐dimethylpent‐2,4‐(trimethylsilyloxy)‐1,4‐diene. This procedure gave oligomers with silyl enol ether end groups. The silyl enol ether groups r