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Reaction of mercury salts with dimethyl tricyclo [4.2.2.02,5]deca-3,7-diene-cis-endo-9,10-dicarboxylate in acetic acid

✍ Scribed by V. R. Kartashov; T. N. Sokolova; T. V. Salikova; Yu. K. Grishin; N. S. Zefirov

Book ID: 105595466
Publisher: Springer
Year: 1999
Tongue: English
Weight: 309 KB
Volume: 48
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf02494865

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## Abstract Acid treatment of 9__exo__‐methyl‐__anti__^10,11^‐tricyclo[4.2.1.1^2,5^]deca‐3,7‐diene‐9__endo__, 10__endo__‐diol (**8**) leads to the two isomeric pentacyclic ethers **7** and **9** by intramolecular nucleophilic substitution of a protonated OH‐group with participation of a C,C‐double