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Reaction of Me3Ga and Me3Al with the tertiary-tetraaza analog of adamantane, hexamethylenetetramine (N4-Ada). Syntheses and molecular structures of [(Me3M)n · N4-Ada] (n = 1–4, M  Ga or Al)

✍ Scribed by Jameica B. Hill; Sheila J. Eng; William T. Pennington; Gregory H. Robinson


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
701 KB
Volume
445
Category
Article
ISSN
0022-328X

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Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]