Reaction of Magnesium Porphyrinates in Polymers Containing Imidazole
✍ Scribed by Dr. S. Besecke; Dr. B. Evans; G. H. Barnett; Dr. K. M. Smith; Dr. J.-H. Fuhrhop
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 240 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
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## Abstract **Summary:** Condensation polymers based on two different NLO‐active chromophores, namely 2‐[4‐[(4‐__N__,__N__‐dihydroxyethylamino)phenylazo]phenyl]‐5(6)‐nitrobenzimidazole (BZI) and 2‐[4‐(4‐__N__,__N__‐dihydroxyethylamino)phenylazo]‐4,5‐dicyanoimidazole (IMI), have been synthesized and
Kinetics of the reactions of imtdazole with u-oxobis(tetrakis(p-su~ophenyl)porphyrinatoiron(III)), VFeTPPS)sOl , and uoxo-bis(tetrakis(p-trimethyl- ammoniumphenyl)porphyrinatoiron(II.I)), [(Fe-TAPP),O] , were investigated at 30 "C and 0.1 F (NaNOJ) ionic strength. The compound (FeTPPS)20 reacts at