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Reaction of lithium diphenylphosphonium di(methylide) with carbonic acid derivatives. A novel access to polyfunctional unsaturated esters and amides

✍ Scribed by Henri-Jean Cristau; Anne Perraud-Darcy; Yves Ribeill


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
678 KB
Volume
3
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

The lithium diphenylphosphonium di(methylide) Ph~2~ P(CH~2~)~2~ Li 1 readily attacks cyclic carbonates, carbamates, and thiocarbamates, resulting in “pseudo‐acylation” products, after a ring‐opening step. Thus, new stabilized ylides are prepared, which can be used in situ as carbonyl olefination reagents towards aldehydes. This procedure is a new one‐pot method for the synthesis of (E)‐vinylic esters and amides, bearing a free ω‐hydroxyl group. When a thiocarbamate is the initial substrate for 1, a Michael‐type cyclization occurs, following the Wittig olefination, resulting in the one‐pot preparation of 7‐membered heterocycles.