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Reaction of iron pentacarbonyl with N,N-diethyl-S-ethylcarbamate; crystal structure of [{Fe(CO)6}3(μ4-S)2(μ-CNEt2)2]3(feFe), a compound containing three butterfly units

✍ Scribed by Helgard G. Raubenheimer; Gert.J. Gruker; Antonie van A. Lombard

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 608 KB
Volume: 323
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(87)80432-1

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo