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Reaction of hydrogen with oxygen, catalyzed by the palladium chloride-dimethyl sulfoxide complex

โœ Scribed by L. Kh. Freidlin; Yu. A. Kopyttsev; N. M. Nazarova; B. L. Khusid; B. L. Lebedev

Book ID
112438921
Publisher
Springer
Year
1974
Tongue
English
Weight
177 KB
Volume
23
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

The reaction of sulfoxides with hydrogen
The reaction of sulfoxides with hydrogen chloride
โœ R.H. Rynbrandt ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 128 KB

The reversible formation of sulfodichloride intermediates (&,) has been proposed to explain the RlR2SO + 2HCl&lR2SC123 + Ii20 (Eq. 1) 1 s racemization of optically active sulfoxides by hydrogen chloride in organic solvents (Eq. 1). 1,2 Mislow' h8S suggested that the symmetrization of the sulfodic