Reaction of heterocyclic aldehydes with methyl derivatives of unsaturatedγ- andδ-lactones
✍ Scribed by D. Jansone; L. Leite; M. Fleisher; J. Popelis; I. Mazheika; E. Lukevics; G. Melikyan; A. Avetisyan
- Publisher
- Springer US
- Year
- 1998
- Tongue
- English
- Weight
- 253 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0009-3122
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📜 SIMILAR VOLUMES
## Abstract A preparatively useful one‐step transformation of __γ__,__γ__‐disubstituted __α__‐formyl‐__γ__‐lactones into trisubstituted __γ__,__δ__‐unsaturated aldehydes is described, by means of catalytic amounts of either AcOH or AcOEt in the vapor phase over a glass support. A mechanistic ration
## Abstract 1‐Trimethylsilyl‐1,3‐diyne derived trans‐bis(trimethylstannyl) enynes undergo stepwise transmetallation with methyllithium to furnish the corresponding enynyllithium reagents. The application, in various orders, of a sequence of transmetallation‐protonation‐alkylation‐hydroxyalkylation‐
## Abstract For Abstract see ChemInform Abstract in Full Text.