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Reaction of Grignard Reagents with Dianionic Hexacoordinated Silicon Complexes: Organosilicon Compounds from Silica Gel

✍ Scribed by Alain Boudin; Dr. Geneviève Cerveau; Dr. Claude Chuit; Prof. Dr. Robert J. P. Corriu; Dr. Catherine Reye


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
351 KB
Volume
25
Category
Article
ISSN
0044-8249

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✦ Synopsis


RSiR;: The suspension of 1 in ether was treated with an excess (3.6 equivalents) of organometallic reagent. After the addition, the mixture was refluxed for 1 h and then hydrolyzed with H2S04 (25%). The silane was then extracted as described above.