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Reaction of [Fe 2 (CO) 8 (μ-CF 2 )] with AsMe 3 and Other Lewis Bases: Syntheses, Crystal Structures of [Fe(CO) 6 (AsMe 3 ) 2 (μ-CF 2 )] and [Fe(CO) 5 (AsMe 3 ) 3 (μ-CF 2 )], and Theoretical Considerations

✍ Scribed by DelaVarga, Meritxell; Petz, Wolfgang; Neumüller, Bernhard; Costa, Ramon


Book ID
127276967
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
311 KB
Volume
45
Category
Article
ISSN
0020-1669

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Preparation, Spectroscopic Properties, a
✍ W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 253 KB 👁 1 views

The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri