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Reaction of ethyl ethylene phosphite with 1,1,1-trifluoroacetone

โœ Scribed by A. M. Kibardin; T. Kh. Gazizov; P. I. Gryaznov; A. N. Pudovik

Book ID
112442235
Publisher
Springer
Year
1979
Tongue
English
Weight
150 KB
Volume
28
Category
Article
ISSN
1573-9171

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Reaction of Ethyl 4,4,4-Trifluoroacetoacetate Enolate with 3-Bromo-1,1, 1-trifluoroacetone: Synthesis of 2,4-Bis(trifluoromethyl)furan. -The title reaction follows competing courses such as C-acylation, O-alkylation and di-O-alkylation which result in the formation of two major products (III) and (I