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Reaction of ethyl cyclopropanecarboxylate with base

โœ Scribed by Pinnick, Harold W.; Chang, Yeong-Ho; Foster, Scott C.; Govindan, Meledath

Book ID
126335109
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
463 KB
Volume
45
Category
Article
ISSN
0022-3263

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โœ E. Ghera; Y. Ben-David ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 223 KB

Ethyl 4-bromocrotonate reacts as a Michael acceptor with carbanions derived from phenylsulfones and B-ester sulfides; the conjugated addition is followed by the displacement of Br-affording various cyclopropanecarboxylates. In reactions of sulfur-containing carbanions with a,B-unsaturated y-bromoes