𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reaction of dinuclear thiolato-bridged cobalt compounds with activated alkynes. Formation and X-ray structure of an unusual trinuclear cobalt complex, [Co3(η5-C5H5)3(SMe)2(CF3CCCF3)2]

✍ Scribed by F.Y. Pétillon; J.L. Le Quéré; F. Le Floch-Pérennou; J.E. Guerchais; P. L'haridon

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
859 KB
Volume
281
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Complexes of the (Tetramethylcyclobutadi
Complexes of the (Tetramethylcyclobutadiene)cobalt Fragment with Boratabenzene Ligands and an Unprecedented Formation of a Borabenzene Complex − Structures of (C4Me4)Co(3,5-Me2C5H3BSnMe3) with an Sn−B Bond and of the Dinuclear Complex [(C4Me4)Co(3,5-Me2C5H3B)]2O
✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th