## Previous work of Hansson and Rasmusson (1) has shown that low concentrations (lO-' M) of ascorbic acid enhance the rate of purified milk acid phosphatase catalyzed hydrolysis of phenyl phosphate by 500/o, and that higher concentrations of ascorbic acid (lo-'M) are completely inhibitory. It was
Reaction of Dicyanocobyrinic Heptamethyl Ester with Ascorbic Acid
✍ Scribed by Doz. Dr. Albert Gossauer; Dipl.-Chem. Burghard Grüning; Dr. Ludger Ernst; Dipl.-Chem. Wulf Becker; Doz. Dr. William S. Sheldrick
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 202 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The ^13^C‐NMR chemical shifts of dicyanocobyrinic acid heptamethyl ester (**1**), an important corrinoid model compound, are correlated with those of some derivatives. Isotope effects on the ^13^C chemical shifts (over two to four bonds) are observed for the 10‐deuterio and the 10,13‐di
The biological and pharmacological activity as well as the therapeutic potential of l-ascorbic acid and its derivatives have been studied extensively. [1] However, despite the fact that l-ascorbic acid possesses several interesting functionalities, the organic chemistry and synthetic potential of th
Chemistry of L-Ascorbic Acid. Part 2. The Paterno-Buechi Reaction of L-Ascorbic Acid. -The Paterno-Buechi reaction of protected ascorbic acid is investigated and applied to the synthesis of ketohexose derivatives like (VI). -(THOPATE,