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Reaction of diazomethane with the palladium(II) chloride complexes of 2,2,N,N-tetramethyl-3-buten-1-amine and 2,2-dimethyl-3-buten-1-yl methyl sulfide. Carbene insertion

✍ Scribed by Robert McCrindle; David W. Sneddon


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
526 KB
Volume
282
Category
Article
ISSN
0022-328X

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## Abstract Two monomeric cobalt(II) complexes, [CoL(N~3~)]ClO~4~ (1) and CoL(N~3~)~2~ (2), where L is tris((3,5‐dimethylpyrazol‐yl) methyl) amine, were synthesized and their crystal structures were determined by X‐ray diffraction technique. Complex 1 is five coordinated with one azide nitrogen ato