Reaction of Deuterium with Hydrocarbons Over a Cobalt—Thoria Fischer—Tropsch Catalyst 1
✍ Scribed by Thompson, Sydney O.; Turkevich, John; Irsa, Adolph P.
- Book ID
- 126136082
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 437 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Natural gas and coal are converted to fuels by the Fischer-Tropsch reaction, i.e., by reacting CO with H 2 , the currently accepted mechanism involving surface carbide formation. We have monitored the adsorbed species and their evolution during Fischer-Tropsch reaction on the commercial catalyst Pt,
Step-change experiments between H,, CO, and syngas mixtures with time resolution of ca. 0.3 s were undertaken to critically test mechanisms proposed in the literature for the Fischer-Tropsch synthesis. A silica-supported cobalt catalyst was used. Results suggest C,, olefins and branched paraffins fo