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Reaction of Cp(CO) 2 ReRe(CO) 2 Cp with Alkynes Produces Dimetallacyclopentenones Cp(CO) 2 Re(μ-η 1 ,η 3 -CRCR‘CO)Re(CO)Cp Which React with Acid To Form Cationic Bridging Vinyl Complexes

✍ Scribed by Casey, Charles P.; Cariño, Ronald S.; Sakaba, Hiroyuki

No coin nor oath required. For personal study only.

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Reaction of Cp*(CO) 2 ReRe(CO) 2 Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO) 2 Re(μ-η 1 ,η 3 -CRCR‘CO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes