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Reaction of copper acetylides with tetracyanoquinodimethane and tetracyanoethylene

✍ Scribed by L. Yu. Ukhin; A. M. Sladkov; Zh. I. Orlova


Book ID
112433272
Publisher
Springer
Year
1969
Tongue
English
Weight
178 KB
Volume
18
Category
Article
ISSN
1573-9171

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Organocatalytic SOMO reactions of copper
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## Abstract The derivatisation of aldehydes in their Ξ±-position is an important facet of organic synthesis. Organocatalytic radical reactions afford Ξ±-functionalised aldehydes via a SOMO activation pathway. New organo-SOMO reactions of aldehydes with copper(I)-acetylide and alkylindium reagents are