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Reaction of carbonyl-stabilized selenonium ylides with derivatives of some group V trivalent elements

โœ Scribed by B. A. Arbuzov; Yu. V. Belkin; N. A. Polezhaeva; G. E. Buslaeva


Book ID
112449916
Publisher
Springer
Year
1979
Tongue
English
Weight
176 KB
Volume
28
Category
Article
ISSN
1573-9171

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The reduction of the tetrachloroaurate (111) anion by L (L = PPh,, AsPh,, SbPh,) is quantitative in non-aqueous solution. The products are the gold(1)-complexes AuClL (L = AsPh,, SbPh,) and Au(PPh,)$ together with the corresponding oxidation product LCI,. Kinetic studies show that the reactions are