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Reaction of carbohydrate 1,2-orthoesters with complex alcohols

โœ Scribed by N. I. Uvarova; N. F. Samoshina; G. I. Oshitok; G. B. Elyakov

Book ID
112480618
Publisher
Springer
Year
1975
Tongue
English
Weight
94 KB
Volume
24
Category
Article
ISSN
1573-9171

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โœ Beat Ernst; Alain De Mesmaeker; Beatrice Wagner; Tammo Winkler ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

Carbohydrate exe 1,2-or&esters are obtained in good to excellent yields by treatingjiuanose andpyranose hemiacetalsfirst with 1.1 eq. I-chloro-2,N,N-trimethyl-propenylamine and then with the appropriate alcohols in the presence of NEg.