Reaction of C60 and C70 with molecular oxygen
✍ Scribed by M. Wohlers; H. Werner; D. Herein; T. Schedel-Niedrig; A. Bauer; R. Schlögl
- Book ID
- 116136969
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 339 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0379-6779
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Cm and Cm sektiiz tbt photoiuygenation of Z-methyl-2-butcne ar well as (E)-2+netity&2qentene-I ,I,1 d3 by the intermediacy of singlet oxygen Addition of DABCO rainces substantially the mte of photooxygenatiorrllw regio-and stereoselectivity of these m.0n.v are repwed
## Abstract The reactions of C~60~ and C~70~, dissolved in toluene, with ozone at 100, 23.5, 0. ‐ 16, and ‐ 78°C are reported. Both fullerenes are transformed swiftly at all of these temperatures. Both fullerenes form monoxides, dioxides and possibly higher oxides. The ratio of the rate parameters