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Reaction of bicyclo[3.2.1]octa-2,6-diene with 1,2,4-triazoline-3,5-diones: competitive dipolar and homocycloaddition

โœ Scribed by Adam, Waldemar; De Lucchi, Ottorino; Peters, Karl; Peters, Eva Maria; Von Schnering, Hans Georg


Book ID
126267241
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
743 KB
Volume
104
Category
Article
ISSN
0002-7863

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Reaction of bicyclo[3.2.1]octadiene with
โœ Waldemar Adam; Ottorino De Lucchi ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

The nonconjugated bicyclo[3.2.l]octa-2,6-diene (1) affords with 4-methyl-1,2,4-triazolin-3,5-dione (MTAD) the homo-cycloadduct (2) product and the rearranged urazoles ( 2) and ( 2) through dipolar cycloaddition, while ene-reaction and (2+2)-cycloaddition are not observed. Bicyclo[3.2.l]octa-2,6-die