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Reaction of benzyne with benzene

โœ Scribed by Stiles, Martin; Burckhardt, Urs; Freund, Guenter


Book ID
121298651
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
332 KB
Volume
32
Category
Article
ISSN
0022-3263

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Ye wish to report the hitherto unknown reaotlcm of benzyne with carbon dleulilde to @~a thlQanlSOle, thloqgenol and dlnhenyl sulfide. Hetalllo sodlum and liquid amnontd were stirred for 1 hr and, Into the resultant dark-violet solution was added an appropriate amount of carbon dlsul?lde durlw 7 min

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A recent paper on the title subject by Tabushi et al 1 prompts us to record our results in this area. Thermal decomposition of o-bensenediasonium carboxylate in the presence of cycloheptatriene yields two Cl3~12 isomers. One of these is 7-phenylcycloheptatriene 2, and the other,a cycloadduct to whic