Reaction of aziridines with benzoic anhydride
โ Scribed by Loewrigkeit, P.; Del Franco, G. J.; Georgalas, N.; Resnick, P.
- Book ID
- 127196811
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 458 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Reactions of aziridines and epoxides with acetic anhydride catalyzed by an organophosphine provided the corresponding esters of b-amino alcohols and 1,2-diols in high yields, respectively.
## Abstract For Abstract see ChemInform Abstract in Full Text.
A new reactibn involving carbon-carbon bond cleavage of the aziridine ring has been observed. Refluxing of 1, 2, J-triphenylaziridine(') (I) with diethylacetylene dicarboxylate in toluene for eleven hours forms 1,2,5-triphenyl-3,4-dicarbethoxy-3-pyrroline(II) in 98% vield. I Recrystallization from e