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Reaction of Aryl Iodides with (PCP)Pd(II)—Alkyl and Aryl Complexes: Mechanistic Aspects of Carbon—Carbon Bond Formation

✍ Scribed by Heinz-Bernhard Kraatz; Milko E. van der Boom; Yehoshoa Ben-David; David Milstein


Book ID
119922794
Publisher
Laser Pages Publishing Ltd.
Year
2001
Tongue
English
Weight
106 KB
Volume
41
Category
Article
ISSN
0021-2148

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Reaction of zirconacyclopentadienes with one equiv or two equiv of aryl iodides in the presence of CuCI and DMPU afforded mono-arylated diene derivatives in high yields with high selectivities. Treatment of zirconacyclopentadienes with one equiv of 2-thienyl iodide similarly gave thienyldienes in th