Reaction of arenediazonium tetrafluoroborates with 3-(allyloxy)propane-1,2-diol and 2,2-bis(allyloxymethyl)butan-1-ol in the presence of thiocyanates
✍ Scribed by B. D. Grishchuk; V. S. Baranovskii; Ya. P. Koval’skii; P. M. Gorbovoi
- Book ID
- 106522571
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 48 KB
- Volume
- 74
- Category
- Article
- ISSN
- 1070-3632
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## Abstract In THF solution, NaBH~4~ in the presence of (__S__)‐(‐)‐1‐(2‐chlorophenyl)‐2,2‐dimethylpropane‐1,3‐diol together with 2‐chlorobenzoic acid reduced propiophenone to 1‐ phenylpropan‐1‐ol in up to 40% enantiomeric excess (__ee__). Only 21% __ee__ was obtained without an added acid. (__R__)
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