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Reaction of an open-chain analogue of reissert compound hydrofluoroborate salt with ethyl acrylate. A reinvestigation

✍ Scribed by Sandrine Perrin; Karin Monnier; Bernard Laude; Marek M. Kubicki; Olivier Blacque


Book ID
104258838
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
108 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction of an open-chain analogue of Reissert compound hydrofluoroborate salt with ethyl acrylate does not give a [4+2] cycloadduct as previously described, but a [3+2] cycloadduct which evolves to a 2-pyridone 15.


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Reactions of the Hydrofluoroborate Salts
✍ Sandrine Perrin; Karin Monnier; Bernard Laude; Marek Kubicki; Olivier Blacque πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 245 KB πŸ‘ 1 views

## The reaction of the hydrofluoroborate salt of an open-chain The [3 + 2] cycloadducts 13 evolve via a rearrangementcondensation sequence to give a substituted 2-pyridone analogue of a Reissert compound with some Ξ±,Ξ²-ethylenic esters does not give a [4 + 2] cycloadduct, as previously derivative 1