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Reaction of Amide Acetals with Isocyanates. The Synthesis of Parabanic Acid O,N-Acetals

✍ Scribed by Prof. Dr. H. Bredereck; Dr. G. Simchen; cand. chem. E. Göknel

Publisher
John Wiley and Sons
Year
1964
Tongue
English
Weight
124 KB
Volume
3
Category
Article
ISSN
0044-8249

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✍ Dr. R. Feinauer 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB 👁 1 views

The reactivity of the aziridinium cation towards the hydroxyl group of alcohols and phenols makes possible a simple synthesis of 2-alkoxyethylamines 111. If the reaction is carried out with a-hydroxy esters ( I ) and aziridinium tetrafluoroborate (2), one obtains first the salts (3) and then, by lo