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Reaction of aluminum isopropoxide with dialkyl methylphosphonates

โœ Scribed by K. A. Andrianov; A. S. Shapatin


Book ID
112436768
Publisher
Springer
Year
1962
Tongue
English
Weight
231 KB
Volume
11
Category
Article
ISSN
1573-9171

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The rate of nucleophilic substitution at the phosphorus centre of dialkyl methylphosphonates by methoxide and ethoxide has been studied to investigate the possible involvement of hexacoordinated phosphorus species in this reaction. For alkoxide concentrations less than ca. 1.5 M the rate increases w