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Reaction of Allyl Halides with Diazomethane Catalysed by Copper Salts

✍ Scribed by Prof. Dr. W. Kirmse; Dipl.-Chem. M. Kapps


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
206 KB
Volume
4
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Highly Substituted Homoallylvinylcyclopr
✍ Stephen M. Capps; Timothy P. Clarke; Jonathan P. H. Charmant; Henning A. F. Höpp 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 477 KB

Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with α,β-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side