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Reaction of alkylhydrazines. 3. Reaction of methylhydrazine and 1,1-dimethylhydrazine with cis- and trans-cyclohexane-1,2-dicarboxylic anhydrides. Products and reaction sequence

โœ Scribed by Kasina, Sudhakar; Nematollahi, Jay


Book ID
126188005
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
328 KB
Volume
42
Category
Article
ISSN
0022-3263

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A new reactibn involving carbon-carbon bond cleavage of the aziridine ring has been observed. Refluxing of 1, 2, J-triphenylaziridine(') (I) with diethylacetylene dicarboxylate in toluene for eleven hours forms 1,2,5-triphenyl-3,4-dicarbethoxy-3-pyrroline(II) in 98% vield. I Recrystallization from e