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Reaction of alkyl orthotitanates with titanium tetrachloride in a piperidine medium

โœ Scribed by A. N. Nesmeyanov; R. Kh. Freidline; E. M. Brainina


Book ID
112490611
Publisher
Springer
Year
1955
Tongue
English
Weight
355 KB
Volume
3
Category
Article
ISSN
1573-9171

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Efficient acetalisation of aldehydes cat
โœ Angelo Clerici; Nadia Pastori; Ombretta Porta ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 502 KB

The acetalisation of aliphatic and aromatic aldehydes is achieved in a basic medium by using catalytic amount of Ti(IV) chloride in MeOH in the presence of NH3 or EhN. The present protocol shows many advantages over the well known base or acid catalysis: in fact. in contrast to base-promoted aoetali