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Reaction of alkoxythallium(III) compounds of olefins with palladium(II) chloride. Evidence of Tl?Pd exchange in oxymetallates

✍ Scribed by Uemura, Sakae; Zushi, Kazuo; Okano, Masaya; Ichikawa, Katsuhiko


Book ID
121823877
Publisher
The Royal Society of Chemistry
Year
1972
Tongue
English
Weight
127 KB
Volume
4
Category
Article
ISSN
0022-4936

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✍ Adrien T. Normand; Mikhail S. Nechaev; Kingsley J. Cavell 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 505 KB

## Abstract A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η^3^‐C~3~H~5~)(tmiy)(PR~3~)]BF~4~ (tmiy=tetramethylimidazolin‐2‐ylidene, PR~3~=phosphane), precursors to monoligated Pd^0^ species, with aryl electrophiles yielding 2‐arylimidazolium salt is reported. Experiments e