Reaction of alkenes with iodine(I) thiocyanate
β Scribed by Paul D. Woodgate; Ho H. Lee; Peter S. Rutledge; Richard C. Cambie
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 252 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with
A simple and efficient thiocyano-or isothiocyano-phenylselenenylation of alkenes has been developed. The reactions occur when alkenes are treated with [bis(acetoxy)iodo]benzene, trimethylsilyl isothiocyanate or potassium thiocyanate and diphenyl diselenide. Mono-and disubstituted alkenes led to the