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Reaction of alkanethiols with 1-trialkylsilyl, 1-trialkylgermyl, and 1-trialkylstannyl derivatives of 2-substituted acetylenes

✍ Scribed by M. G. Voronkov; R. G. Mirskov; V. I. Rakhlin

Book ID: 112439719
Publisher: Springer
Year: 1975
Tongue: English
Weight: 220 KB
Volume: 24
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00927472

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## Abstract 1‐Aza‐2‐azoniaallene cations 3, prepared in situ from geminal chloro(alkylazo) compounds 2, react with acetylenes 4 to give either 1__H__‐pyrazolium salts 6 or 4__H__‐pyrazolium salts 7 or mixtures of both. 4__H__‐Pyrazolium salts with a hydrogen atom attached to C(4) rearrange to the p